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But lower tire pressure better traction, all other things equal. 45psi is high for a Car, trucks often have higher pressure for the same reasons bicycles have higher tire pressure, less roll resistance and thus better gas mileage (or in the case of a bicycle, easier pedaling).
I would hesitate going with anything higher than what your car manual is suggesting, for the simple reason your car was designed to operate THAT TIRE AT THAT PRESSURE. In some cars the tire pressure makes no difference, in others critical (for example the early Corvairs were very sensitive to tire pressure and the chief reason their were "unsafe", the same with the M151 series of Vietnam era Jeeps).
Volvos are a well built and designed car, if the tires are marked 50 PSI, but the car manual is saying 38, Volvo has to have some reason for the difference. It may be that the suspension of the Volvo depends on the lower inflation number to meet the the comfort level Volvo wanted, or it can mean that at high speeds and/or turnings the tire will gets so warm that it will "explode" and thus Volvo wants the lower figure to provide a sufficient safety "cushion".
Given the higher Gas prices in Europe (and Volvo is marketed for European Drivers as while as American Drivers) I lean to Volvo Just wanting to preserve some safety margin. Remember as a tire rotates as the car is driven, the air pressure in the Tire heats up and expands INCREASING THE TIRE PRESSURE. Volvo may believe that if you keep the tire at 38psi when the tire heats up the tire will NOT go over its maximum pressure and burst. Perelli may believe that the correct pressure is 50, so to get maximum fuel efficiency with its tires.
Given the above I would lean to stay with the 38psi, unless I learn for sure (and you never will) that the concern was comfort not safety.
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