Science
Related: About this forumAn obscure fact I never knew: All of the lanthanides except promethium exhibit a divalent state.
I was wandering around the scientific literature today and came across this very cool fact:
I added the bold.
Trimethylsilyl versus Bis(trimethylsilyl) Substitution in Tris(cyclopentadienyl) Complexes of La, Ce, and Pr: Comparison of Structure, Magnetic Properties, and Reactivity (Chad T. Palumbo, Lucy E. Darago, Cory J. Windorff, Joseph W. Ziller, and William J. Evans, Organometallics 2018 37 (6), 900-905)
Most surprising in this equation is the fact that this holds true for three actinides, thorium, uranium and plutonium. Weird.
I'm glad I found that out before I died.
Karadeniz
(22,511 posts)eppur_se_muova
(36,260 posts)So that's some pretty powerful reducing going on.
NNadir
(33,513 posts)...like they've been around for quite some time.
At a first glance, they look like electrides, with which I have some familiarity in relation to radiation chemistry.
Some of the fun of writing here is that people sometimes tell me things I didn't know; often it's you who does so.
Thanks again.
eppur_se_muova
(36,260 posts)IIRC, there was an article on this in Scientific American when I was in high school -- or maybe not. I just know I came across it at a time when I knew enough about chemistry to find such a thing almost unthinkable. Alkali metals were always cations! But someone thought otherwise. If I search my old notes I might find a record of a lecture from grad school on cryptands, so it's been brought to my attention a couple of times.
https://en.wikipedia.org/wiki/Alkalide
Then there's this:
Less common oxidation states of gold include ?1, +2, and +5.
The ?1 oxidation state occurs in aurides, compounds containing the Au? anion. Caesium auride (CsAu), for example, crystallizes in the caesium chloride motif;[39] rubidium, potassium, and tetramethylammonium aurides are also known.[40] Gold has the highest electron affinity of any metal, at 222.8 kJ/mol, making Au? a stable species.[41]
https://en.wikipedia.org/wiki/Gold#Rare_oxidation_states
and this:
https://www.sciencedirect.com/science/article/pii/S129325580500230X
Apparently both BaPt and Cs2Pt are known.
Oh, and Pekka Pyykö (I love that name!) has predicted that Oganesson - element 118, a "noble gas" element, should form an anion - good thing IUPAC gave that name the nonmetallic -on ending!
keithbvadu2
(36,778 posts)lastlib
(23,217 posts)Ah, chemistry! (and I had to be a Math geek............)