All recycling is
superficially not economic - if you ignore external costs - as long as virgin uranium is under a few hundred bucks a kilo.
PBR fuel is designed to be stable under very extreme conditions, including conditions of high temperature - and because it is designed to be a vehicle for so called "nuclear waste" - under extreme chemical conditions as well. Both of these features are counter productive to recycling.
I have had some conversations with nuclear professionals recently who claim that PBR fuel
can be recycled, but I note that there is no infrastructure to do so.
I am sure that it
could be accomplished technically. Fluorine chemistry - not the nicest chemistry but chemistry that has
always been a part of the nuclear fuel cycle - suggests itself. However it would seem to me that it would be unnecessarily difficult. Using flourine chemistry with
carbon always presents a risk of the production of carbon tetrafluoride. PBR fuel is carbon based, using both graphite and silcon carbide. While this carbon tetrafluoride is nontoxic, its atmopheric lifetime is
extremely long - and it is a potent greenhouse gas. Although the energy density of uranium is extraordinarily high, meaning that chemical effects are likely to be small, these things have a way of adding up over the long term. Thus it is entirely possible that the rather silly 21st century obsession with so called "nuclear waste" - an obsession that is in part the justification for PBR fuel - could involve some very long term atmospheric consequences.
It behooves us to look at the
true external costs of energy. I suspect that the external cost of recycling PBR fuel would be higher than the external costs of recycling light water reactor fuels.
It would also seem to me that the external and internal cost of recycling molten salt reactor fuel would be extraordinarily low, much lower even than the external cost of recycling light water reactor fuel. I believe this type of reactor will prove to dominate the latter part of this century if there
is a latter part of this century at all.
I do not think that current recycling chemistry for light water reactors - the PUREX process - is necessarily the last or best word on the subject. I would suspect that molten salt chemistry and/or electrorefining will displace PUREX wet chemistry in the future, even before molten salt
reactors become widespread technology. There may be circumstances under which PBR type fuels could be incorporated into such schemes - but I am not an expert and do not know.
Interestingly the production of carbon tetrafluoride has been an issue in some types of solar cell manufacture. Of course, the actual production of solar cells has been trivial but if - and I doubt this will happen in the next decades - solar energy were to become a
significant source of energy, the external cost - including things like carbon tetrafluoride - will be correspondingly larger. Here is a comment by a person at Brookhaven National Laboratory who is a specialist on the external cost of solar energy:
http://findarticles.com/p/articles/mi_m0CYP/is_1_110/ai_83445535There are no significant environmental and safety hazards with any of (the types of solar cells) to the scale that they are manufactured today," he explains. And although there are some hazardous materials used, such as silane gas, cadmium, carbon tetrafluoride, and lead, he says, "if you look at the quantities in relation to their use in other industries, they are very, very small." But these risks will become more significant as the industry grows, he adds.
The bold is mine.