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NNadir

NNadir's Journal
NNadir's Journal
July 17, 2021

Periodic Table As Seen By Organic Chemists.



I saw this on Linkedin, posted by a very senior guy at Lilly.

I will confess to having been an organic chemist, although at this point in my career, near the end, I'm more an analytical chemist.

We're really not entirely this shallow when it comes to the chemistry of the elements - samarium does some cool organic chemistry, as does, for that matter, cerium (Who cares?) - but I found it hilarious overall.

I recall a lecture by Barry Trost, a very famous organic chemist, where he had a periodic table, "The Periodic Table According to Trost," which featured palladium in much the same way as carbon is depicted here. (Catalysts I use to do real chemistry.)

Loved "fake elements made up by commies" since the second heaviest of them is named for Tennessee. I never thought of Tennessee as a communist country. (106 is named for the great American Chemist, Glenn Seaborg.)
July 17, 2021

Investigation of Poverty at the Russell Sage Foundation



Alice Neel, Oil on Canvas, 1933.

On Loan to the Metropolitan Museum of Art NY, Alice Neel, People Come First, March 22 - August 1, 2021

Part of the Permanent Collection of the Pennsylvania Academy of Fine Arts, Philadelphia, Pennsylvania.
July 15, 2021

President Carter is among roughly 350,000 "liquidators" involved in nuclear reactor "clean ups."

Of course, he had no involvement in Chernobyl, but in the early 1950s, fuel rods at the Chalk River Nuclear NRX Research Reactor in the Ottawa Valley region of Ontario partially melted. (December 1952). It was the first melt down of a nuclear reactor in history of which we know. The experience of the future President nonetheless is rather similar to the experience of the roughly 350,000 Soviet Military Personnel involved in the Chernobyl clean up; it involved short exposure to possibly intense radiation to move highly radioactive components of a failed reactor.

This Stanford under graduate student's term paper describes Carter's experience there: Carter at Chalk River

A CNN piece around the time of Fukushima, when Carter was 86 years old, directly quoted the former President on this experience: Jimmy Carter's exposure to nuclear danger

"We were fairly well instructed then on what nuclear power was, but for about six months after that I had radioactivity in my urine," President Carter, now 86, told me during an interview for my new book in Plains in 2008. "They let us get probably a thousand times more radiation than they would now. It was in the early stages and they didn't know."

Despite the fears he had to overcome, Carter admits he was animated at the opportunity to put his top-secret training to use in the cleanup of the reactor, located along the Ottawa River northwest of Ottawa.

"It was a very exciting time for me when the Chalk River plant melted down," he continued in the same interview. "I was one of the few people in the world who had clearance to go into a nuclear power plant," he said.

"There were 23 of us and I was in charge. I took my crew up there on the train..."

..."It was the early 1950s ... I had only seconds that I could be in the reactor myself. We all went out on the tennis court, and they had an exact duplicate of the reactor on the tennis court. We would run out there with our wrenches and we'd check off so many bolts and nuts and they'd put them back on.

And finally when we went down into the reactor itself, which was extremely radioactive, then we would dash in there as quickly as we could and take off as many bolts as we could, the same bolts we had just been practicing on. Each time our men managed to remove a bolt or fitting from the core, the equivalent piece was removed on the mock-up..."


(Later President Carter, while President, would walk through the Three Mile Island Reactor while the situation was, excuse the pun, fluid, much to the consternation of the Secret Service.).

I mention this as an indication of how difficult it is to ascertain the "true numbers" associated with the exposure to radioactivity at Chernobyl. President Carter is the oldest of four siblings, and is the only one of them who is still alive. The other three, Ruth Carter Stapleton, Gloria Carter, and "Billy" Carter all died, Ruth in her 50's, from the same disease, pancreatic cancer.

As an advocate of nuclear energy, I could point to this anecdotal evidence about President Carter and make the specious claim that being exposed to a nuclear meltdown, two in Carter's case, the big bogeyman at Three Mile Island included, is a potential way to protect people with a clear familial history of pancreatic cancer, for them to avoid dying from the disease. This of course would be exceedingly misleading, since we really don't know what effect, if any, his participation in the clean ups had on his pancreas cells. It might be that is other three siblings inherited a different set of genes from their parents than he did.

On the other hand, if President Carter were to die at the age of 100, a nuclear opponent could easily claim that he would have lived to 110 if he hadn't cleaned up Chalk River and toured Three Mile Island while its core was melting. Some of them are indeed this stupid.

This points out something about the complexity of your excellent question.

I personally very much doubt that the "death toll" - which involves considerable complexity to discern - associated with Chernobyl is "under 50." I would expect a higher figure, although the figure is nowhere near the figures I was trained to believe would result by stupid journalists, anti-nuke "activists," the curious fellows at the poorly named so called "Union of Concerned 'Scientists'" - an organization I joined at one point in my life without making any reference whatsoever to whether I was a journalist, someone who never passed a college level science course with a grade of C- or better, or whether I was a Nobel Laureate Physicist. No information was required to join; the only thing required was sending a check.

In fact, that the observed results of the accident, the serious study of which led me to leave the class of dumbass anti-nukes and join the class of nuclear energy advocates, played a huge role in my current opinions on the topic, since I compared lazy expectations based on general reading from weak sources, to observed reality from legitimate sources.

This topic is covered by vast scientific literature. I would refer to an excellent journalistic consideration of bias among anti-nukes and pro-nukes like myself, by Mary Mycio, a Ukrainian-American author who traveled to Chernobyl in the early years after the accident to flesh things out for herself: Wormwood Forest A Natural History of Chernobyl (2005) It's not all that technical, but as a social science document, I found it excellent, and on the part of nuclear advocates, I felt a bit chastised myself.

An excellent overview of the scientific consequences, including mortality, is found the "UNSCEAR report" put together by the United Nations Scientific Committee on the Effects of Atomic Radiation." The tortured bureaucratic name of this committee suggests some level of irony. Here's a link to the 2008 report: Annex D, Health Effects Due to Radiation from the Chernobyl Accident. The list of references to the primary scientific literature starts on page 205 and ends on page 219 in relatively small print.

Of course, anti-nukes completely dismiss this report, since they apparently believe that Chernobyl wiped out Kiev and most of Eastern Europe, in fact, and parts of Scotland.

If it said that two million people died from Chernobyl - it doesn't - I of course, engage in "whataboutism" by noting that millions of people die in a continuous fashion from air pollution, which is also continuously dismissed by faith based anti-nukes in this (and other) space. A recent related post on the subject of Diablo Canyon I made on this site produced, as well I should expect, stupid accounts of the geological faults near the plant, pointing to an unrealized risk being elevated to the obvious effects of climate change in that State.

This is why Ms. Mycio's book is, in my view, a "must read" for anyone considering bias in this discussion.

It is clear to me, nonetheless, that whatever the risks of nuclear energy - and they are very real - these risks pale in comparison to the vast and observed risks of not using nuclear energy.

I could write for hours on the topic of radiation exposure, which has been included in my work over the last 30 years, and may at some point take the liberty of saying more in this space, or at least refer to my earlier writings on the topic, but the question is not, as the anecdotal evidence of President Carter's experience as a "liquidator" in the early 1950's suggests, simply answered.

Thanks for your excellent question. Stay tuned.
July 14, 2021

Where I Work: Chernobyl.

This news item came in my Nature Briefing Email this morning, in Nature's "Where I Work" Series in the news sections.

WHERE I WORK

12 July 2021

Tracking Chernobyl’s effects on wildlife

Evolutionary ecologist Germán Orizaola Pereda analyses how species have been affected, 35 years after the world’s worst nuclear accident.

(Virginia Gewin, Nature 595, 464 (2021))

The accompanying picture:



It's probably open sourced, and it's brief. A few exceprts:

Thirty-five years after the explosion and meltdown at the Chernobyl Nuclear Power Plant in Ukraine, I study how amphibians in the region have changed, physically and genetically. In 2016, I joined an international research team to do this; since then, I have obtained various grants to continue the work. Chernobyl is a phenomenal place to study rapid evolution. I typically spend two to three weeks in the forests during the frogs’ spring breeding season.

...When I work in the ‘exclusion zone’, the 4,700 square kilometres around the reactor, I stay in a hostel in Chernobyl (20 kilometres from the reactor site), where we have a field laboratory inside an abandoned building. The radiation in the exclusion zone is roughly 1,000 times lower than at the time of the accident, and there are now two hostels, a bar, a couple of restaurants and a cash machine. In this image, I’m running a blood analysis on one of the tree frogs we have collected. The contamination maps on the wall behind me show that some hotspots of radiation persist...

...Once expected to become a wasteland, the Chernobyl area is now a nature reserve. New species have arrived, including European bison (Bison bonasus) and the wild Przewalski’s horse (Equus ferus przewalskii). We’re beginning to monitor these horses, originally from the Asian steppes: the effects on their health could be a proxy for what happens when humans return. The first 31 horses were released here in 1998, 12 years after the disaster, and it is one of the few places where they continue to live freely.


Dr. Germán Orizaola Pereda's Google Scholar hits are few in number and are mostly in Spanish.

Here, however, is a very nice article in English:

FROM NUCLEAR DESERT TO EVOLUTIONARY LAB

It is open sourced, I think.

Subtitle: The response of living organisms to Chernobyl’s ionising radiation.

An excerpt from this much longer interesting report:

...One revealing case in the current situation of Chernobyl’s Exclusion Zone wildlife is that of Przewalski’s horses. These wild horses were not present at the time of the accident, but a herd of around 30 specimens was released in 1998–1999. The goal was that their feeding activities would control the forest expansion towards old cultivation lands. This population remains completely isolated within the Exclusion Zone, and they cannot reach any other horses of the same species coming from the outside. Nonetheless, 20 years after their introduction into Chernobyl, the population has increased fivefold and over 150 Przewalski’s horses now live in the Zone. Another example of the optimal condition of this population is its high reproduction rate, with 22 foals born in 2018...


I oppose recent discussions on reopening the exclusion zone to human habitation, although it is clear that some humans have defied the ban and moved into the exclusion zone.
July 13, 2021

Busbar Electricity Prices at the Tehachapi Wind Farm This Evening.

The "Busbar" price of electricity is the price paid more or less at the generation source where it connects to the grid. It is more or less equivalent to the Incoterm FOB.

The California ISO website has a map based report of pricing at all California Power plants. It is here: Real Time Electricity Pricing.

The Tehachapi "wind resources area" has a Wikipedia page, describing its size and capacity: Tehachapi Wind Resource Area

Here is some interesting text from that Wikipedia page:

It is the largest wind resource area in California, encompassing an area of approximately 800 sq mi (2,100 km2) and producing a combined 3,507 MW of renewable electricity between its 5 independent wind farms.


800 square miles...2,100 sq km, 3,507 MW. I accept these as "facts," but if someone would like to suggest, "alternate facts," feel free to do so.

On the pricing page linked, you have to move the cursor over the plant, whereupon pricing will pop-up at that plant. The five Tehachapi wind plants are located pretty much due East of Pismo Beach, near the town of Mohave. You can zoom in and out to isolate it using the + and - keys at the bottom of the map. The prices at power plants change with market flows and are tied to the load of the State of California. As of this writing, 19:30 PDT, 6:30 PM, the State of California is consuming 37,449 MW of electricity, down from the peak demand at 18:00 PDT (6:00 PM PDT) of 38,709 MW. As of 19:30 PDT, all of the wind facilities in the entire State of California, including but not limited to the Tehachapi wind resources area were producing 4,678 MW of power. At the low point today, which occurred at 12:10 PDT, (12:10 PM PDT), at which all of the wind facilities in the entire State of California, including but not limited to the Tehachapi wind resources area were producing 1,319 MW of power, or roughly 0.5 MW per square mile if we, without real justification, imagine that all of California's wind turbines were in the Tehachapi Wind Resource Area Industrial Park. Actually this stuff is spread over a much larger area of the State of California.

Here, by the way, is an aerial view of part of the marvelous wind plant:



Notice all those delicious service roads for diesel trucks. Delicious...

Some prices at the plants as of 17:40 PDT (6:40 PM):

ENCWND: $77.49/MWh.
North Wind $77.09/MWh
TOT162W4_7_N001 $77.51/MWh.
ALTAD2_7_N006 $77.94/MWh.
ARBWIND_6_N001 $77.73/MWh

The Diablo Canyon Nuclear Plant operates as a physical plant, on 12 acres, (0.018 sq miles or 0.049 sq km) on a plot of around 700 acres (1.1 sq miles or 2.2 sq km), most of which is undisturbed marine chaparral. The plant has been producing between 2261 MW (low) and 2267 MW (high) consistently and reliably all day long, as of 18:30 PDT, July 12, 2021. In other words, the land footprint of the Diablo Canyon Nuclear Plant is 0.1% that of the Tehachapi Wind Resources Area.

The Diablo Canyon Nuclear Plant is located on the California coast, just north of Pismo Beach, and South of Morro Bay.

As of 20:05, the plant's busbar operating cost was:

DIABLOCN_2_N001: $82.68/MWh

This by the way is a lower price than is being observed at the nearby Dangerous Natural gas plants nearby in Pismo Beach

CALLENDR_1_N001 $85.06/MWh.

OCEANO_1_N004 $85.04

...and slightly higher than the price at the Morro Bay dangerous natural gas plant, $82.45/MWh.

At 18:30 PDT (6:30 PM PDT), dangerous natural gas plants in California were producing 21,133 MW of power.

Note that electricity prices swing wildly during the day, depending on load and supply for all power plants. These prices apply to an early evening on a hot day.

Note that the prices observed at Diablo Canyon do not include, as the wind plants should but don't, the costs associated with the necessary back up plants. It doesn't matter at Diablo Canyon if the wind is blowing or the sun is shining. The Diablo Canyon, unlike the gas plants, is able to contain all of its by products, the very valuable used nuclear fuel, on site, in contrast to the dangerous natural gas plants, which are allowed to dump the dangerous fossil fuel waste carbon dioxide directly into the planetary atmosphere at no cost, except for the cost to all future generations and all living things as a result of extreme climate change.

The State of California is now tragically experiencing more wild fires, as it has done in several recent years with increasing regularity. To my mind this is a function of the fact that the half of century of jaw boning about how wind and solar energy would save the world didn't work, isn't working and won't work, if the goal is to address climate change.

If, on the other hand, the goal is to lace the desert with access roads, the "renewable energy" industry in California is doing just great.

Because of appeals to fear and ignorance and wishful thinking, the Diablo Canyon Nuclear Plant will begin closing in 2024, and will stop producing climate change gas free electricity for the California grid.

Have a nice day tomorrow.
July 12, 2021

My Funny Valentine

?t=2035
July 11, 2021

Raging Bootleg Fire in Oregon threatens vital Northern California power grid lines

I noticed on the Supply Page for the CAISO , which reports real time data on the status of the power grid in California, that Northern California, Southern California and the VEA (part of the Nevada grid) are all under warning status for the grids.

Here is the text of one of the warning notices:

Current Active Notice(s)

CAISO Grid WARNING NOTICE [202102550]

The California ISO hereby issues a CAISO Grid WARNING Notice,
effective 07/10/2021 17:00 through 07/10/2021 21:00.

Reason:
CAISO has lost resources due to fire and is anticipating hig|h loads.

CAISO is forecasting a resources deficiency with all available resources in use or forecasted to be in
use for the specified time period. If not already declared, CAISO may request the Reliability
Coordinator to declare an EEA-1.

If the Emergency Demand Response Programs are dispatched, then CAISO may request the
Reliability Coordinator to declare an EEA-2.

Conservation efforts are encouraged for the time period specified in this notice. Energy Market
Participants are encouraged to offer additional Supplemental Energy and Ancillary Service bids.

Refer to the CAISO System Emergency Fact Sheet
(http://www.caiso.com/Documents/SystemAlertsWarningsandEmergenciesFactSheet.pdf) for
additional detail.

Monitor system conditions on Today's Outlook
(http://www.caiso.com/TodaysOutlook/Pages/default.aspx) and check with local electric utilities for
additional information.

Notice issued at: 07/10/2021 12:33


Famously the West Coast is and has been experiencing extreme temperatures, and the notice refers to fires.

The fires are described in this news item:

Raging Bootleg Fire in Oregon threatens vital Northern California power grid lines

The text of the CBS News item:

With soaring temperatures already pushing California's power grid to the limit, utility officials were keeping a weary eye on the Bootleg Fire that is raging out of control in southern Oregon and threatening Path 66 — a vital electric line corridor linking the state with the Oregon power grid.


The fast-growing wildfire has prompted mandatory evacuations, threatening about 3,000 homes. Pushed by strong winds, the fire's burn zone in Klamath County has grown to more than 61 square miles. There was no containment, CBS SF Bay Area reports.

"The fire will continue to move unchecked in all direction with unstable air conditions and extremely dry fuels," the National Forest Service said...

...CAISO and other grid operators were monitoring the fire as it was burning in the proximity of the California Oregon Intertie — also known as Path 66. It's a corridor of three parallel 500kV power lines that connects the power grids of Oregon and California.

The three lines are owned by PG&E, PacifiCorp, the Western Area Power Administration and the Transmission Agency of Northern California. PG&E officials on Friday activated the utility's Emergency Operations Center to monitor the situation and manage any eventualities...


...and so on...

Some people, I would be one of them, believe that the extreme temperatures which have been causing extreme droughts and extreme fires are extremely tied to the complete and total failure of humanity to address climate change.

It's now 109°F, (43°C) in Bakersfield, CA, with highs predicted to exceed 110°F through Wednesday of this week.

As of 18:10 PDT (6:10 PM PDT), the California Grid is reporting the following status, with extra special note of all that so called "renewable energy:"

40,427 MW
Current demand

12,497 MW
Current renewables

6,340 MW
Current solar

4,297 MW
Current wind

Interestingly, the supply page makes no note in these prominently displayed headlines of the power source that is currently dominating the power supply in California, easily outstripping both magical solar and wind combined. That would be dangerous natural gas. Dangerous natural gas is providing 21,430 MW of power. You have to look at the fine print.

Why speak of unpleasant things? Sweep 'em under the rug...we're "green."

Dangerous natural gas is composed largely of the powerful climate forcing gas methane, which is combusted to drive turbines whereupon the powerful climate forcing gas methane is converted to the less powerful climate forcing gas, the dangerous fossil fuel waste carbon dioxide. Although molecule for molecule, methane is a more powerful climate forcing gas, some people, I would be one of them, believe that the extreme West Coast temperatures are driven more by carbon dioxide than methane, since there is far more carbon dioxide in our international fossil fuel waste dump, the planetary atmosphere, than methane.

The removal of the dangerous fossil fuel waste carbon dioxide from the waste dump, the planetary atmosphere, will require producing all of the energy now being generated to keep the air conditioners in California running, plus the energy to reverse the entropy that burning the dangerous natural gas produced. The energy to do this will be required to be generated by future generations who will be living in a burned out wasteland, in which all of the world's best ores have been mined and dumped, much of it in connection with "renewable energy."

Good luck kids...we have been so sure you could do it "by 2050" or "by 2045" or "by whatever year it is when we'll be dead and won't be concerned with our failure to care about you" that we didn't bother to do it ourselves.

Speaking "by 'such and such'" a year, "by 2024" the Diablo Canyon Nuclear Plant, which is not driving climate change but is, as of this writing producing 2,266 MW of climate change gas free power, will be shutting down because of appeals to fear and ignorance, coupled to extreme wishful thinking and a healthy dollop of denial, a situation that if it had prevailed today would mean that California would be providing 21,430 + 2,266 MW = 23,596 MW of electricity by burning dangerous natural gas and dumping the dangerous natural gas waste carbon dioxide directly into the atmosphere.

In two small buildings, the Diablo Canyon nuclear plant is producing more energy that can be provided by three truck lines from burning Oregon. It operates on 12 acres of land as a physical plant, situated on a 700 acre plot of largely undisturbed marine chaparral.

As of 18:25 PDT (6:25 PM PDT), today California has dumped 1,738,530 metric tons of the dangerous fossil fuel carbon dioxide into the planetary atmosphere to power its grid, which unsurprisingly in the age of celebration of lies, is described as "green." It dumped 10,892 tons in the last five minutes.

The state is laced with ton upon ton upon ton upon ton of copper wires to hook all this "green" stuff together. One hopes they don't melt.

History will not forgive us, nor should it.
July 10, 2021

Graphic Update On How We're Doing With Carbon Dioxide.

My working number for the amount of the dangerous fossil fuel waste carbon dioxide we dump each year, carbon dioxide being only one component for such waste, not quite the deadliest yet, but getting there, has been 35 billion metric tons per year. Being a lazy sort of person, I just let that number, gleaned from general reading, gel in my head for a number of years, without searching out a formal reference to support that number. I kept muttering to myself that I really should update that number, but I didn't do it.

I had an inkling that I might be out of date - old people get used to being "out of date," - when I attended a lecture by Dr. Robert Kopp of Rutgers University a few years ago, this one: Science on Saturday: Managing Coastal Risk in an Age of Sea-level Rise. Dr. Kopp gave a higher figure in his lecture, and in the QA, I questioned him on it and he pointed to the issue of land use. Later, I see in my notes, I emailed him for a reference, and he graciously responded the reference which provides the graphic below, but somehow I forgot about it -


This morning, going through a journal I read regularly, Environmental Science and Technology, and came across this paper, which posits that we could do better than capturing 90% of the carbon dioxide we release, and find some place to dump it eternally, although there is zero evidence that we have ever come remotely close to doing so, and zero evidence that we could find a place to dump hundreds of billions of tons of this waste, permanently, ultimately trillions of tons in such a way that no one on Earth, irrespective of their level of education, could ever imagine it ever escaping and injuring anyone at any time in the future stretching for the entire tenure of the human race on this planet. The paper's first reference is the one that Dr. Kopp shared with me some time ago while I continued to lazily mutter, "35 billion tons a year." I'll produce the nice graphic from that reference shortly.

That paper is here: Deep CCS: Moving Beyond 90% Carbon Dioxide Capture (Matthew N. Dods, Eugene J. Kim, Jeffrey R. Long, and Simon C. Weston, Environmental Science & Technology 2021 55 (13), 8524-8534)) Three of the authors are from UC Berkeley, one, Dr. Weston, is from, unsurprisingly, Exxon.

The financial disclosure statement in the paper reads as follows:

The authors declare the following competing financial interest(s): J.R.L. has a financial interest in and serves on the board of directors of Mosaic Materials, a start-up company working to commercialize metal-organic frameworks for gas separations.


Exxon, which funded this work, apparently claims it has no financial interest in this paper, since it has been able, for free, at no cost, to dump vast quantities of dangerous fossil fuel waste into the planetary atmosphere, where such waste from Exxon and other companies, kills millions of people per year, and is completely destroying the planetary atmosphere, although Exxon has spent huge amounts of money claiming, weakly and transparently, that this is no big deal.

Note that this standard I applied above to the capture and storage of dangerous fossil fuel waste above, is the standard that people apply to so called "nuclear waste." People who have no idea about the nature and composition of used nuclear fuels, which in the United States, after more than half a century of operation, amounts to around 80 thousand metric tons. To repeat, that standard is:

...in such a way that no one on Earth, irrespective of their level of education, could ever imagine it ever escaping and injuring anyone at any time in the future, stretching for the entire tenure of the human race on this planet.


People who complain loudly about so called "nuclear waste," never apply this standard and ask this question about dangerous fossil fuel waste when they start their cars in the morning. I am acutely aware of this.

Eighty thousands is written in scientific format 8 X 10^(4). The rate at which used nuclear fuel is becoming available to future generations increased for many years, and has regrettably leveled off but the average accumulation per year, over say, 64 years, beginning with the Shippenport Nuclear Power Plant - which was located on ground that is now a public park - in 1957, up to the present day, amounts to about 1200 tons per year, in scientific notation, 1.2 X 10^(3). By the way, in scientific notation, 35 billion tons, my lazy figure, is 3.5 X 10^(10). The ratio of 10^(10) and 10^(3) is 10^(7), or ten million. Each year, according to my lazy figure, we dump, at no charge to the dumper, ten million times as much dangerous fossil fuel waste on the planet as a whole, than the United States has been accumulating, on average - although the current rate is much higher than the average rate - of used nuclear fuel, so called "nuclear waste."

There is about 4000 tons of used nuclear fuel at the idle San Onofre Nuclear Plant in California. It has killed none of the surfers who routinely surf just beyond the plants borders. The composition of this used fuel is roughly between 95% and 96% actinide elements, chiefly uranium, with about 1% being plutonium, and smaller amounts of the valuable elements neptunium, americium, and perhaps trace amounts of curium. If one assumes a working figure of 200 Mev/fission for these actinides, which works out to 80 trillion joules per kg, one can calculate that the energy value of the actinides available at this single shut plant is on the order of 300 exajoules, the energy consumption very roughly of the entire United States for just under 3 years.

Yet people who know very little about what so called "nuclear waste" is and who couldn't care less about its spectacular record of over more than half a century of killing very few people, in any, and also couldn't care less about what to do with the dangerous fossil fuel waste released when they start their engines, dangerous fossil fuel waste having killed hundreds of millions of people since 1957 when the Shippenport reactor came on line, claim "nobody knows what to do with nuclear waste."

They could disabuse themselves of this notion by opening science books and scientific papers, but that's too much to ask.

I have no room to talk: I lazily use the figure of "35 billion tons" for the amount of the dangerous fossil fuel waste carbon dioxide dumped each year, for free albeit at the expense of every living thing, including human beings, forever, by humanity.

The figure in Weston et al, Weston of Exxon, is 40 billion tons per year, not 35 billion tons. What's 5 billion tons between friends?

I'm such a lazy person.

The reference in Weston et al, which Dr. Kopp shared with my lazy ass two years ago, albeit probably to an earlier version of this series is this one: Global Carbon Budget 2019 (Earth Syst. Sci. Data, 11, 1783–1838, 2019) This paper is open sourced, and the list of authors and their institutions is too long to repeat, which is understandable, given the magnitude of the task of figuring this matter out.

The promised graphic is this one:



The caption:

Figure 3Combined components of the global carbon budget illustrated in Fig. 2 as a function of time, for fossil CO2 emissions (EFF, grey) and emissions from land use change (ELUC, brown), as well as their partitioning among the atmosphere (GATM, blue), ocean (SOCEAN, turquoise), and land (SLAND, green). The partitioning is based on nearly independent estimates from observations (for GATM) and from process model ensembles constrained by data (for SOCEAN and SLAND), and it does not exactly add up to the sum of the emissions, resulting in a budget imbalance, which is represented by the difference between the bottom pink line (reflecting total emissions) and the sum of the ocean, land, and atmosphere. All time series are in gigatonnes of carbon per year. GATM and SOCEAN prior to 1959 are based on different methods. EFF is primarily from Gilfillan et al. (2019), with uncertainty of about ±5?% (±1? ); ELUC is from two bookkeeping models (Table 2) with uncertainties of about ±50?%; GATM prior to 1959 is from Joos and Spahni (2008) with uncertainties equivalent to about ±0.1–0.15?GtC?yr?1 and from Dlugokencky and Tans (2019) from 1959 with uncertainties of about ±0.2?GtC?yr?1; SOCEAN prior to 1959 is averaged from Khatiwala et al. (2013) and DeVries (2014) with uncertainty of about ±30?% and from a multi-model mean (Table 4) from 1959 with uncertainties of about ±0.5?GtC?yr?1; SLAND is a multi-model mean (Table 4) with uncertainties of about ±0.9?GtC?yr?1. See the text for more details of each component and their uncertainties.


Note that this figure gives the values in elemental carbon, not carbon dioxide. The atomic weight of carbon is roughly 12, the molecular weight of carbon dioxide is roughly 44. This translates 12 billion tons of carbon to 43 billion tons of carbon dioxide.

I started paying some small attention to environmental issues when I read the very stupid paper by the very stupid anti-nuke Amory Lovins in 1976: Energy Strategy, the Road Less Traveled. Of course that the time I read it, I was a very stupid young man, as opposed to the very lazy, hopefully less stupid, old man I am now. Being credulous in my youth, I bought into the notion that the very stupid anti-nuke Amory Lovins was in fact, a "genius," a status applied by the media to him as a result of him being awarded the "MacAuthur Prize," the so called "Genius" award. Amory Lovins contention was that we could save the world with so called "renewable energy" and energy conservation, the latter claim expressing contempt for the billions of people who lacked any access to industrial energy then and now.

Of course, as a believer in the rhetoric of the very stupid anti-nuke Amory Lovins, I was anti-nuclear. I changed my view of nuclear energy to "not so bad," around 1988, after analyzing the scientific data available in the literature to which I had access, coming out of the Chernobyl disaster, which established the previously unknown, yet often evoked, "worst case."

I still believed that so called "renewable energy" was a good thing, probably for another decade or so.

I changed my mind about that as well, since this affectation has soaked up trillions of dollars, requiring vast amounts of dangerous fossil fuels to be burned to support it, vast wildernesses rendered into industrial parks, and huge mining operations to embrace it, all for no other result than making the situation get worse faster.

I think the case that this effort has been a failure is graphically indicated in the graphic above, which I have been too lazy to access.

Go figure.

But then again, this is the age of the celebration of the lie. After all, a cheap lying carney barker completely devoid of a trace of ethics and disinterested in matters of faith, was elected to the office once held by Abraham Lincoln, and celebrated by people who consider themselves "faithful" arbiters of morality, morality apparently consisting of vast faith in White Supremacy.

Of course, people have vast faith that so called "renewable energy" will save the world, a reactionary premise equivalent in my mind to the reactionary 19th century premise that White People, a vast cabal of murderers and imperialists, were morally superior to other people as they waited for Jesus to be resurrected. Now we are resurrecting the idea that by returning to the practices of the 18th century, when pretty much everyone lived on whatever "renewable energy" could provide, most people living short miserable lives of dire poverty, we will save the world.

So called "renewable energy" has not saved the world. It is, again, graphically as graphically shown above, not saving the world. My personal, albeit lazy, analysis suggests it will not save the world.

History will not forgive us; nor should it.

Have a nice weekend.
July 9, 2021

Reliability-Wary California Will Procure More Energy Resources to Get It Through Summer

This news item comes from a Trade Journal, Power to which I subscribe, even though I'm not in the power industry.

Stricken by repeated extreme heat events, the prospect of a worsening drought, incremental resource delays, and the “unforeseen” loss of 300 MW in thermal resources, California has set out to secure additional energy resources to ensure reliability this summer.

Responding to a June 29 letter from the California Public Utilities Commission (CPUC) and the California Energy Commission (CEC), the California Independent System Operator (CAISO) on July 1 declared a “significant event” and used its backstop capacity procurement mechanism (CPM) authority to issue a solicitation for additional capacity during the months of July, August, and September. However, CAISO officials in a July 2 call suggested the significant event may last through October.

CAISO’s declaration of a CPM significant event is notable because it means the grid operator has determined that current conditions are “materially different” from assumptions it used to determine resource adequacy capacity requirements—and that those conditions threaten the grid’s reliability. While CAISO uses the authority sparingly, it declared a similar event last summer during an intense heatwave when it was forced to implement periods of rotating blackouts in various places throughout the state on Aug. 14 and 15...

...Among the state’s recent efforts to address summer reliability is a Feb. 11–issued decision (D.21-02-028) by the CPUC that directed the state’s three largest investor-owned utilities (IOUs)—Pacific Gas and Electric (PG&E), Southern California Edison, and San Diego Gas & Electric—to contract for additional capacity to serve peak and net peak demand this summer. That decision, pivotally, allowed the utilities to source incremental capacity from existing power plant efficiency upgrades; revised power purchase agreements; contracts for generation that is at risk of retirement; incremental energy storage capacity; and “firm” forward imported energy. And while that order did not specify a megawatt procurement target, the CEC said it has “expeditiously reviewed and approved incremental capacity at jurisdictional gas plants to support this procurement...”

...Of most concern is that the West is facing a severe drought that has reduced hydro capacity by about 1 GW, they said. While CAISO in its May-issued 2021 Summer Loads and Resources Assessment (SLRA) warned that hydro conditions would be “below normal,” resource conditions have quickly deteriorated. At Lake Oroville, for example, the state’s second-largest reservoir, water levels have fallen to 30% of capacity, and the California Department of Water Resources warned the water could be so low in a few months that the Butte County reservoir’s hydroelectric generating plant may be forced to shut down for the first time.

The CEC and CPUC also said natural gas power resources have declined. “Due to unforeseen circumstances, at least 300 MW of thermal capacity will not be available this summer,” it noted. At the same time, the state is facing critical incremental resource delays. “The CPUC recently received notice that several will be delayed by one to several months, and in some cases will push online dates past the summer window,” it noted...


Then there's this delicious bit of fantasy:

...The CPUC’s measure last month is partly rooted in the state regulator’s 2020-initiated effort to ensure enough capacity to replace 3,700 MW from natural gas generators, which are expected to retire owing to California’s once-through-cooling rules, and 2,700 MW from PG&E’s two Diablo Canyon nuclear reactors, which are slated to go offline in 2024 and 2025. The CPUC specifically ordered 2.5 GW of zero-emitting resources to replace Diablo Canyon’s generation, along with generation paired with storage, or demand response resources, but it said that all resources that LSEs can procure “will be zero-emitting, unless they otherwise qualify under the renewables portfolio standard eligibility requirements.” That may include 1 GW of new geothermal resources, as well as 1 GW of long-duration (8 hours or more) storage resources, which the CPUC envisioned should come online by 2025. It may also include some biomass...


"Some" biomass. Even if all the forests in California burn outside of a power plant?

The solution: A pile of batteries the size of Mt. Whitney, which should keep our cobalt digging slaves in the "Democratic" "Republic" of Congo, happily employed.

California's energy supply increasingly depends on the weather and lacing the state with copper wires while jaw boning about batteries laced with lithium obtained by mining, cobalt, nickel and/or manganese, obtained by mining, filled with ketones made from pentanone from petroleum or natural gas, and, "imports" of, gas power.

The performance of the CAISO grid is available in real time here: CAISO Today's Outlook

The data is shown graphically, but can also be obtained by clicking on the "download" buttons next to each graphic in the supply, demand, and other headings. This downloads a CSV file (spreadsheet, Excel compatible) showing values in 5 minute intervals beginning at midnight.

I have taken the liberty of doing this as of 17:30 California time for supply, and 17:40 for demand.

Some data, as of 2021, in a year where a town in British Columbia, Canada, caught fire in extreme heat, which is hardly the only disaster connected with this heat wave, where temperatures routinely climbed well above 40C.

The peak demand, recorded at 17:40 PDT (5:40 PM) in California, (the last time point as of my download, which should be very near the predicted peak) was 40,684 MW. At that time so called "renewable energy" was producing, as of 17:30 PDT, (5:30 PM PDT), was producing 11,240 MW of power, dominated by the falling output of solar energy, as the sun falls toward the horizon, which at 17:35, was producing 7697 MW.

The minimum demand for the grid 23,591 MW, recorded at 4:00 PDT (4:00 AM). At that time, so called "renewable energy" in the entire State of California was producing 4,571 MW, dominated by wind power, which at that time was producing, 2,933 MW, assisted by a fairly consistent (throughout the day) 937 MW of geothermal power.

The average power demand up to 17:40 PDT on July 8, 2021 was 30,140 MW

The highest output of all so called "renewable energy" facilities in the State of California was observed at 14,774 MW, observed at 11:55, when the demand in the entire State of California was 32,118 MW. The lowest output for so called "renewable energy" for the entire State of California was observed at 6:00 PDT (6:00 AM PDT), was 3,210 MW, when the demand was 25,202 MW. The continuous average for so called "renewable energy" in California 9,532.6 MW.

The differences in these cases, except for nuclear power and small amounts of (threatened) large hydro, was made up by burning dangerous natural gas, obtained partly by fracking, with the dangerous fossil fuel waste carbon dioxide being dumped directly into the planetary atmosphere, this after half a century of cheering wildly for so called "renewable energy" in California, this at a time where for a long stretch of time, temperatures greater than 43C were observed in the State.

The peak production of all the dangerous natural gas powered generators in the State of California, was 20,421 MW, observed at 17:30 PDT (5:30 PM PDT). The minimum power production from California's dangerous natural gas plants was 9,177 MW, at 4:10 PDT (4:10 AM PDT). The average power output of the dangerous natural gas plants in the State of California was 12,455 MW. As of 18:55 PDT (6:55) the amount of dangerous fossil fuel waste carbon dioxide dumped by the State of California into the planetary atmosphere was 1,952,238 metric tons. Considering entropy, more energy than was produced by burning this dangerous fuel will be required to remove this dangerous waste from the atmosphere. This is a consequence of the laws of thermodynamics, which no one seems to know, at least if you read the crap written by journalists about energy.

Batteries, batteries, hydrogen, hydrogen...Jesus Christ!

The Diablo Canyon nuclear plant, the last nuclear plant in California, due to shut because of appeals to fear and ignorance produced at it's peak today, 2,273 MW. It's minimum was 2,268 MW and its average was 2270 MW. It is connected to the grid with just a few high tension wires, and all of the copper in its turbines, and all of the metals in its magnets was in continuous use, requiring no redundant systems. The physical plant is situated on 12 acres, but the property, mostly untouched marine chaparral, is 750 acres.

In the period between 0:00 PDT and 17:35, a period of 17 hours and 35 minutes, the two small buildings at the Diablo Canyon Nuclear Power Plant were producing more power than all of the wind turbines, spread over god knows how much former wilderness in the entire State of California, for 12 hours and 40 minutes of that period.

The Diablo Canyon Nuclear Plant has a thermal efficiency of about 33%. I have convinced myself that nuclear power plants can be designed to equal or exceed the efficiency of combined cycle dangerous natural gas plants, which can run at 60% or higher. Thus a nuclear plant with the same land footprint as Diablo Canyon might be capable of producing 4,500 MW of power, perhaps higher.

This suggests that two such footprints for two such plants could reliably and continuously, without fluctuation, produce as much as the average power produced by all the so called "renewable energy" in California, and that 10 such plants could reliably produce the power peak demand experienced by California on July 8, 2021, without burning a single molecule of dangerous natural gas.

The same media that told you Donald Trump was Presidential material, also reports that anti-nukes are "environmentalists."

We live in the age of the celebration of the lie.

Have a nice day tomorrow.



July 5, 2021

Scientists quit journal board protesting 'grossly irresponsible' study claiming COVID-19 vaccines...

...kill.

I almost hesitate to post reference to this article, since I attended a lecture by neural biologists Sam Wang in which he suggested that repeating a lie, even noting that it is just that, a lie, gives it some level of credence.

(To wit: Our media and Trump's lies going back to before he was allowed to destroy American intellectual and moral infrastructure.)

This is a news item in the prestigious scientific journal Science (it's probably open sourced), shades of the ignorant Jenny McCarthy/Robert F. Kennedy Jr lie about autism and vaccines:

Scientists quit journal board, protesting ‘grossly irresponsible’ study claiming COVID-19 vaccines kill Science News, By Meredith Wadman Jul. 1, 2021):

Some excerpts of the news item:

Several reputed virologists and vaccinologists have resigned as editors of the journal Vaccines to protest its 24 June publication of a peer-reviewed article that misuses data to conclude that “for three deaths prevented by [COVID-19] vaccination, we have to accept two inflicted by vaccination.”

Since Friday, at least six scientists have resigned positions as associate or section editors with Vaccines, including Florian Krammer, a virologist at the Icahn School of Medicine at Mount Sinai, and Katie Ewer, an immunologist at the Jenner Institute at the University of Oxford who was on the team that developed the Oxford-AstraZeneca COVID-19 vaccine. Their resignations were first reported by Retraction Watch.

“The data has been misused because it makes the (incorrect) assumption that all deaths occurring post vaccination are caused by vaccination,” Ewer wrote in an email. “[And] it is now being used by anti-vaxxers and COVID-19-deniers as evidence that COVID-19 vaccines are not safe. [This] is grossly irresponsible, particularly for a journal specialising in vaccines.”

The paper is a case of “garbage in, garbage out,” says Helen Petousis-Harris, a vaccinologist who directs the Vaccine Datalink and Research Group at the University of Auckland and who also resigned as a Vaccines editor after reading the paper. Diane Harper, an epidemiologist at the University of Michigan, Ann Arbor, who was founding editor-in-chief of Vaccines, also resigned, as did Paul Licciardi, an immunologist at Murdoch Children’s Research Institute in Parkville, Australia, and Andrew Pekosz, a respiratory virologist at the Johns Hopkins University Bloomberg School of Public Health.

The resignations began Friday, the day after the paper was published. By early Monday, Fanny Fang, the journal’s managing editor, wrote to the editorial board members that Vaccines—a reputable open-access journal launched in 2013 by Basel, Switzerland–based publisher MDPI—had opened an investigation into the paper. “We are treating this case with the utmost seriousness and are committed to swiftly correcting the scientific record,” she wrote...

...The paper has drawn nearly 350,000 readers as of 1 July and has been tweeted by antivaccination activists with hundreds of thousands of followers.

None of the paper’s authors is trained in vaccinology, virology, or epidemiology. They are: Harald Walach, a clinical psychologist and science historian by training who describes himself as a health researcher at Poznan University of Medical Sciences in Poland; Rainer Klement, a physicist who studies ketogenic diets in cancer treatment at the Leopoldina Hospital in Schweinfurt, Germany; and Wouter Aukema, an independent data scientist in Hoenderloo, Netherlands.

The three peer reviewers on the paper, two of them anonymous, did not offer any substantial criticism of the authors’ methodology in these brief reviews. One of them, Anne Ulrich, a chemist who directs the Institute of Biological Interfaces and is chair of biochemistry at the Karlsruhe Institute of Technology in Germany, wrote that the authors’ analysis “is performed responsibly … and without methodological flaws … and the results were interpreted with the necessary caveats.”


I have added the bold.

Most scientists know from experience that "peer reviewed" does not necessarily mean "correct," and even less, "infallible." Over the years here, and elsewhere, I've had people challenge things I know to be true by pointing to a "peer reviewed" paper with more than a little credulity.

It is very clear that as we live in the age of the celebration of the lie, that we should not rely on any one person or group in drawing on very complex issues, including, but hardly limited to issues in Vaccination, Covid, etc. I note that our media is doing a very poor job on covering these issues well, just as they did a terrible job with repeating Trump's outrageous lies, going back to the time Obama was President.

I've written on my own historical credulity in this space: 828 Underground Nuclear Tests, Plutonium Migration in Nevada, Dunning, Kruger, Strawmen, and Tunnels

This case is clearly over the top however; the journal has lost a lot of credibility by publishing such garbage. I almost feel as if the journal should fold.

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